using System;

using System.Collections.Generic;

using System.IO;

using System.Data;

using System.Xml;

using System.Xml.Linq;

//https://stackoverflow.com/questions/46785572/xml-file-with-the-same-tag-name-and-diffrent-values/46786501#46786501                    

public class Program

{

    public static void Main()

    {

        var xml =@"

        <ind>

        <Name>

            <value> a1 </value>

        </Name>

        <Name>

            <value> a2 </value>

        </Name>

        <Name>

            <value> a3 </value>

        </Name>

        <Name>

            <value> a4 </value>

        </Name>

    </ind>

";

        XDocument xdoc = new XDocument();

        //xdoc= XDocument.Load("file.xml"); read from file

        xdoc = XDocument.Parse(xml); //read from string

        List<string> Names = new List<string>();

        var result = xdoc.Descendants("Name");

         foreach (var item in result)           

             Names.Add(item.Value);

        //create datatable

        DataTable dt = new DataTable("table");

        dt.Columns.Add("Name1", typeof(string));

        dt.Columns.Add("Name2", typeof(string));

        dt.Columns.Add("Name3", typeof(string));        

        //fill datatable

        DataRow dtrow = dt.NewRow(); 

        dtrow["Name1"]=Names[0];

        dtrow["Name2"]=Names[1];

        dtrow["Name3"]=Names[2];

        dt.Rows.Add(dtrow);

        //test datatable

         Console.WriteLine("Name1:{0}, Name2:{1},Name3:{2}", 

                          dt.Rows[0]["Name1"],

                          dt.Rows[0]["Name2"],

                          dt.Rows[0]["Name3"]);

    }

}